You only need to fill in the options in use. If you are automatically sending emails to the national body then the SMTP server is needed, and the email address of the national body. Tick the "Automatically send masterpoint files" option and they will be sent.
Also you would need to enter your reply to address, your current email address. Currently the ASE Scorer Version 9 does not receive emails but if needed in the future enter the "Receive mail from host" (POP server) and the corresponding logon-ID and Password.